What's the formula that you are using to transform ADC readings in mV?
Check your voltage divider.
Check your VCC value.
Establish ADC input interval.
Recalibate based on Voltage divider and VCC values.
Reply with the results.
Available on Tindie: https://www.tindie.com/products/nEXT_EVO1/universal-ac-mains-dimmer-mpdmv41/
You know that depending on your VCC your ADC max input voltage is actually about 0.978V, or even less?
Take a look also here: ESP8266 Internal ADC
Available on Tindie: https://www.tindie.com/products/nEXT_EVO1/universal-ac-mains-dimmer-mpdmv41/