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By QuickFix
#76719 Yes you can, that's how a lot of people started their ESP-adventure: simply do a ping or directly connect to the default IP (192.168.4.1) of the ESP.
But it would be better to make the ESP IP configurable (you can use WiFi-manager for this).

As long as your Android app knows the IP of your ESP and you have set it up as AP, you're good to go. :D

[EDIT]
What schufti says is correct, but you can dismiss the "No internet access" warning after connecting to the ESP. :idea: