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By lethe
#21433 The serial bootloader resides on an internal ROM on the ESP. So far, I have not seen any documentation on if or how one would be able to overwrite it. There is a strong possibility, that it's not technically possible to replace the serial bootloader and even if you could, I doubt there would be enough room for a full wifi & IP stack to implement a network bootloader on-chip.
What you can do however is to chain-load a user program from flash to act as secondary bootloader to allow you to flash your ESP via network. However this will not solve your GPIO0/2/15 issues.