It says that for a red led (Vf 2.0) and passing 20 mA, an 68 Ohm resistor will suffice.
You can calculate this yourself if your adventureous:
- subtract the Vf from the supply current (in this case that would be 1.3 V)
- this is the voltage that needs to be over the resistor (so LED + resistor will be add up to 3.3 V)
- Ohm's Law says I = V / R, let's fill it in: 0.020 = 1.3 / R -> R = 65 Ohms.
Microcontroller's GPIOs are almost never a true connect-through to Vcc or GND, it's more like a current source, so you might get away leaving the resistor out, if you're using a LED that has a sufficient high Vf regarding to Vcc. But I'd really rather add a $ 0.01 resistor.