It is not critical but it is in effect in parallel with the 10K (via the base) so will lower the delay time. It could be reduced to 47K or even 22K with small effect. It doesn't want to be too high as the base current needs to be sufficient so that the transistor turns hard on to pull the RST line low. RST has an internal pull up of the order of 10K, so 100K should provide sufficient base current to saturate the transistor.
It is not critical but it is in effect in parallel with the 10K (via the base) so will lower the delay time. It could be reduced to 47K or even 22K with small effect. It doesn't want to be too high as the base current needs to be sufficient so that the transistor turns hard on to pull the RST line low. RST has an internal pull up of the order of 10K, so 100K should provide sufficient base current to saturate the transistor.